Figure 11. Convolution
is used here to determine how the atomic line spectrum in Window 1 (top left)
will appear when scanned with a spectrometer whose slit function (spectral
resolution) is described by the Gaussian function in Window 2 (top right). The
Gaussian function has already been rotated so that its maximum falls at x=0.
The resulting convoluted spectrum (bottom center) shows that the two lines near
x=110 and 120 will not be resolved but the line at x=40 will be partly
resolved.
In practice the
calculation is usually performed by multiplication of the two signals in the
Fourier domain. First, the Fourier transform of each signal is obtained. Then
the two Fourier transforms are multiplied by the rules for complex
multiplication* and the result is then inverse Fourier transformed.
Although this seems to be a round-about method, it turns out to be faster then
the shift-and-multiply algorithm when the number of points in the signal is
large. Convolution can be used as a very powerful and general algorithm for
smoothing and differentiation. The example of Figure 11 shows how it can be
used to predict the broadening effect of a spectrometer on an atomic line
spectrum.
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